Furfural
is an organic compound with
the formula C4H3OCHO.
It is a colorless liquid, although commercial samples are often brown. It has an aldehyde group
attached to the 2-position of furan.
It is a product of the dehydration of
sugars, as occur in a variety of agricultural byproducts,
including corncobs, oat, wheat bran,
and sawdust.
The name furfural comes
from the Latin word furfur,
meaning bran,
referring to its usual source. Furfural is only derived from lignocellulosic
biomass, i.e. its origin is non-food or
non-coal/oil based. Aside from ethanol, acetic acid and sugar it
is one of the oldest renewable chemicals.
It is also found in many processed foods and beverages.
Furfural may be obtained by the acid catalyzed dehydration
of 5-carbon sugars (pentoses), particularly xylose.
C
5H
10O
5 → C
5H
4O
2 + 3 H
2O
These sugars may be obtained from hemicellulose present in lignocellulosic biomass, which can be
extracted from most terrestrial plants.
It is found in many foods: coffee (55–255 mg/kg) and
whole grain bread (26 mg/kg).
Furfural is an important renewable, non-petroleum based,
chemical feedstock. It can be converted into a variety of
solvents, polymers, fuels and other useful chemicals by a range of catalytic reductions.
Hydrogenation of furfural provides furfuryl alcohol (FA), which is
used to produce Furan resins, which are exploited in thermoset polymer matrix composites,
cements, adhesives, casting resins and coatings. Further hydrogenation of
furfuryl alcohol leads to tetrahydrofurfuryl alcohol (THFA),
which is used as a solvent in agricultural formulations and as an adjuvant to help herbicides penetrate the leaf structure.
Another important solvent made from furfural is methyltetrahydrofuran. Furfural is used to
make other furan derivatives, such as furoic acid, via oxidation, and furan itself via palladium catalyzed vapor phase decarbonylation.
Furfural is also a specialized chemical solvent.
There is a good market for
value added chemicals that can be obtained from furfural.
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Furfural |